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Experimental evidence for “hidden intermediates”? Epoxidation of ethene by peracid.

Sunday, August 25th, 2013

Tags: activation free energy, arrow pushing, curly arrow, dichloromethane solution, Dieter Cremer, hidden intermediate, model, using per-ethanoic acid
Posted in Curly arrows, reaction mechanism | 3 Comments »

Hidden intermediates in the (acid catalysed) ring opening of propene epoxide.

Monday, May 6th, 2013

Tags: CF 3 CO, free energy, good model for the subsequent transition state, Interesting chemistry, lower free energy barrier, Reaction Mechanism
Posted in Uncategorised | 1 Comment »

Hidden intermediates in the benzidine rearrangement. The monoprotonated mechanism.

Tuesday, January 8th, 2013

Tags: free energy barrier, Reaction Mechanism
Posted in Uncategorised | 3 Comments »

The mechanism of diazo coupling: more hidden mechanistic intermediates.

Saturday, March 8th, 2014

Tags: covalent systems, first professor, free energy, Imperial College, lowest energy pose, Nick Greeves, professor of chemistry
Posted in reaction mechanism | 2 Comments »

Intermediates in oxime formation from hydroxylamine and propanone: now you see them, now you don’t.

Sunday, April 14th, 2013

Tags: Interesting chemistry, Reaction Mechanism
Posted in Uncategorised | No Comments »

Mechanistic templates computed for the Grubbs alkene-metathesis reaction.

Monday, February 19th, 2024

Posted in Uncategorised | No Comments »

The Pinacol rearrangement.

Tuesday, June 13th, 2023

Posted in Uncategorised | 2 Comments »

One vs two bond rotation – An example using Acyl amides

Monday, April 3rd, 2023

Tags: Interesting chemistry
Posted in Uncategorised | 6 Comments »

A new type of bispericyclic reaction: Cyclopropanone + butadiene.

Friday, September 30th, 2022

Posted in reaction mechanism | No Comments »

Choreographing a chemical ballet: a story of the mechanism of 1,4-Michael addition.

Monday, April 13th, 2020

Posted in crystal_structure_mining, Curly arrows, reaction mechanism | No Comments »

S	M	T	W	T	F	S
			1	2	3	4
5	6	7	8	9	10	11
12	13	14	15	16	17	18
19	20	21	22	23	24	25
26	27	28	29	30	31

Henry Rzepa's Blog

Search Results

Experimental evidence for “hidden intermediates”? Epoxidation of ethene by peracid.

Hidden intermediates in the (acid catalysed) ring opening of propene epoxide.

Hidden intermediates in the benzidine rearrangement. The monoprotonated mechanism.

The mechanism of diazo coupling: more hidden mechanistic intermediates.

Intermediates in oxime formation from hydroxylamine and propanone: now you see them, now you don’t.

Mechanistic templates computed for the Grubbs alkene-metathesis reaction.

The Pinacol rearrangement.

One vs two bond rotation – An example using Acyl amides

A new type of bispericyclic reaction: Cyclopropanone + butadiene.

Choreographing a chemical ballet: a story of the mechanism of 1,4-Michael addition.

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