According to Herges[1],[2] the mechanism of single-step (concerted) reactions can be divided into three basic types; linear (e.g. substitution, elimination etc), pericyclic (e.g. Diels Alder) and a third much rarer, and hence very often overlooked type that was named coarctate. This is based on the topology of bond redistribution patterns, an explicit real example[3] illustrating:
It happens that this reaction bears a close similarity to epoxidation using peracid, the characteristic feature being that the central (spiro) atom has two bonds forming to it and two bonds breaking from it in both reactions.†,‡ I had noted for the latter reaction that in fact the bond redistribution, although concerted, was asynchronous. This asynchrony was represented by the green arrows preceding the blue ones (or vice-versa for the reverse reaction).
So here I decided to investigate if the same might be true of the coarctate reaction shown above (ωB97XD/6-311G(d,p)/SCRF=water.[4]
The transition state is indeed interestingly asynchronous. The O-O bond (shown green above) is clearly the first to break; neither of the C-C bonds has really started to do so at the transition state. But the process remains resolutely concerted.
The IRC above shows clearly that the reaction has a room-temperature barrier (i.e. it is a very facile process). But missing really from this process is any hidden intermediate either (there is the merest hint at IRC = -2). So this reaction is interesting for
† Another example was the topic of this post.
‡ One can contrive an even higher-order reaction (thus far un-named) in which (formally) three bonds break and three bonds form at a single atom.
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Coarctate reactions is really a new concept. I'm still having hard time to understand it :(