A chiral molecular wire.

More than 60 million molecules are known, and many are fascinating. But beauty is in the eye of the beholder. Thus it was that I came across the attached molecule[1]. It struck me immediately as, well, beautiful!

GOCTOH. Click for 3D.

This is one that comes to life in 3D and I strongly urge you to inspect it as such by clicking on the above. Why is it so interesting? Well, it has as its backbone a linear array of seven Nickel atoms. The Ni…Ni distances are around 2.2-2.3Å, and this “wire” is wrapped with a square planar arrangement of nitrogen atoms deriving from the ligand.

But that is not just where I perceived its beauty. The molecule has D4 symmetry, and is therefore dissymetric (chiral). The ligands wrap themselves around the metal wire in a helical arrangement. Oddly, the original authors who reported this lovely molecule make little (nothing?) of this aspect. Can it be resolved for example? Can it recognise other chiral molecules? What are its chiroptical properties (optical rotation, circular dichroism spectra etc)? Anyway enough from me; just go and enjoy this gem! 

Popular Posts:

References

  1. S. Lai, T. Lin, Y. Chen, C. Wang, G. Lee, M. Yang, M. Leung, and S. Peng, " Metal String Complexes:  Synthesis and Crystal Structure of [Ni 4 (μ 4 -phdpda) 4 ] and [Ni 7 (μ 7 -teptra) 4 Cl 2 ] (H 2 phdpda = N -Phenyldipyridyldiamine and H 3 teptra = Tetrapyridyltriamine) ", J. Am. Chem. Soc., vol. 121, pp. 250-251, 1999. http://dx.doi.org/10.1021/ja982065w

Tags:

2 Responses to “A chiral molecular wire.”

  1. […] in the magnetic properties of graphene-like objects (see also this blog post  and also the helical metal wire) such molecules can only help to excite our […]

  2. […] also tried a ball&stick. The molecule selected has been described in another post and is saved by converting the .cif file to .pdb (using in my case the program Mercury). This […]

Leave a Reply