We tend to think of simple hydrocarbons as relatively inert and un-interesting molecules. However, a recent article, which was in fact highlighted by Steve Bachrach on his blog , asks what “The Last Globally Stable Extended Alkane” might be. In other words, at what stage does a straight-chain hydrocarbon fold back upon itself, and no significant population of the linear form remain? The answer was suggested to be C17H36. I thought I might subject this conformation to an NCI (non-covalent-interaction) analysis.
- N.O.B. Lüttschwager, T.N. Wassermann, R.A. Mata, and M.A. Suhm, "The Last Globally Stable Extended Alkane", Angewandte Chemie International Edition, vol. 52, pp. 463-466, 2013. http://dx.doi.org/10.1002/anie.201202894