Henry Rzepa's Blog Chemistry with a twist

December 24, 2016

The dipole moments of highly polar molecules: glycine zwitterion.

The previous posts produced discussion about the dipole moments of highly polar molecules. Here to produce some reference points for further discussion I look at the dipole moment of glycine, the classic zwitterion (an internal ion-pair).

(more…)

September 18, 2011

Some fun with no-go areas of chemistry: cyclobutadiene.

Organic chemistry has some no-go areas, where few molecules dare venture. One of them is described by a concept known as anti-aromaticity. Whereas aromatic molecules are favoured species, their anti-equivalent is avoided. I previously illustrated this (Hückel rule) with cyclopropenium anion. Now I take a look at cyclobutadiene, for which the π-system is said to be iso-electronic (where two electrons in a double bond have replaced the carbanion lone pair).

(more…)

Powered by WordPress