Posts Tagged ‘solvation free energy terms’

Chemical intimacy: Ion pairs in carbocations

Monday, January 11th, 2010

The scheme below illustrates one of the iconic reactions in organic chemistry. It is a modern representation of Meerwein’s famous experiment from which he inferred a carbocation intermediate, deduced from studying the rate of enantiomerization of isobornyl chloride when treated with the Lewis acid SnCl4.