I previously blogged about anomeric effects involving π electrons as donors, and my post on the conformation of 1,2-difluorethane turned out one of the most popular. Here I thought I would present the results of searching the Cambridge crystal database for examples of the gauche effect. The basic search is defined below
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The gauche effect: seeking evidence by a survey of crystal structures.
Friday, January 4th, 2013Tags:basic search, Cambridge, CF 3, conformational analysis, gauche, metal, search takes, similar, Tutorial material
Posted in crystal_structure_mining, Interesting chemistry | 8 Comments »