Linear free energy relationships (LFER) are associated with the dawn of physical organic chemistry in the late 1930s and its objectives in understanding chemical reactivity as measured by reaction rates and equilibria.
Henry Rzepa's Blog
Chemistry with a twist
Trending
- Mechanism of the reduction of a carboxylic acid by borane: revisited and revised.
- Why is the carbonyl IR stretch in an ester higher than in a ketone?
- VSEPR Theory: A closer look at trifluorothionitrile, NSF3.
- The mechanism of the Benzidine rearrangement.
- Oxime formation from hydroxylamine and ketone: a (computational) reality check on stage one of the mechanism.
- Why are α-helices in proteins mostly right handed?
- Mechanism of the Lithal (LAH) reduction of cinnamaldehyde.
- The mechanism of the Birch reduction. Part 1: reduction of anisole.
- The mechanism of diazo coupling: more hidden mechanistic intermediates.
- VSEPR Theory: A closer look at chlorine trifluoride, ClF3.
-
Recent Posts
- The Willgerodt-Kindler reaction. Completing the Box set.
- High-performance polythioesters with high chemical recyclability.
- Exploiting the power of persistent identifiers (PIDs) for locating all kinds of research object.
- The Willgerodt-Kindler Reaction: mechanistic reality check 3. A peek under the hood for transition state location.
- The Willgerodt-Kindler Reaction: mechanistic reality check 2.
Recent Comments
- Rudy on Chemistry in the early 1960s: a reminiscence.
- Joaquin Barroso on Question for the day – Einstein, special relativity and atomic weights.
- Cina on Question for the day – Einstein, special relativity and atomic weights.
- Cina on Question for the day – Einstein, special relativity and atomic weights.
- Henry Rzepa on Question for the day – Einstein, special relativity and atomic weights.
- Peter W on Question for the day – Einstein, special relativity and atomic weights.
- Raphael on Question for the day – Einstein, special relativity and atomic weights.
- Cina Foroutan-Nejad on Question for the day – Einstein, special relativity and atomic weights.
- Andras on Mechanism of the reduction of a carboxylic acid by borane: revisited and revised.
- James Hanson on Woodward’s symmetry considerations applied to electrocyclic reactions.
Blogroll
Previous posts
Categories
Meta
Gravatar
Henry Rzepa
Emeritus Professor of computational chemistry, Imperial College London. http://orcid.org/0000-0002-8635-8390
Henry Rzepa's Blog is proudly powered by WordPress
Entries (RSS) and Comments (RSS).