Henry Rzepa's Blog
Chemistry with a twist
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- Mechanism of the reduction of a carboxylic acid by borane: revisited and revised.
- Oxime formation from hydroxylamine and ketone: a (computational) reality check on stage one of the mechanism.
- The nature of the C≡S triple bond
- Deviations from tetrahedral four-coordinate carbon: a statistical exploration.
- The mechanism of the Birch reduction. Part 1: reduction of anisole.
- Mechanism of the Lithal (LAH) reduction of cinnamaldehyde.
- VSEPR Theory: A closer look at chlorine trifluoride, ClF3.
- The mechanism of diazo coupling: more hidden mechanistic intermediates.
- The conformation of 1,2-difluoroethane
- VSEPR Theory: A closer look at trifluorothionitrile, NSF3.
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Recent Posts
- Curly arrows in the 21st Century. Proton-coupled electron transfers.
- Fascinating stereoelectronic control in Metaldehyde and Chloral.
- The first ever curly arrows. Revisited with some crystal structure mining.
- The strongest bond in the universe: A crystallographic reality check?
- The strongest bond in the universe: revisited ten years on.
Recent Comments
- Henry Rzepa on Reductive ozonolysis: the interesting step.
- lhac on Fascinating stereoelectronic control in Metaldehyde and Chloral.
- Henry Rzepa on Fascinating stereoelectronic control in Metaldehyde and Chloral.
- lhac on Fascinating stereoelectronic control in Metaldehyde and Chloral.
- Henry Rzepa on The first ever curly arrows. Revisited with some crystal structure mining.
- Henry Rzepa on The strongest bond in the universe: A crystallographic reality check?
- Nick Stokes on Chemistry in the early 1960s: a reminiscence.
- John lewis on Chemistry in the early 1960s: a reminiscence.
- Nick on A molecular sponge for hydrogen storage- the future for road transport?
- Sean Davies on Chemistry in the early 1960s: a reminiscence.
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Henry Rzepa
Emeritus Professor of computational chemistry, Imperial College London. http://orcid.org/0000-0002-8635-8390
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