The equilibrium for the hydration of a ketone to form a gem-diol hydrate is known to be highly sensitive to substituents. Consider the two equilibria:
The equilibrium for the hydration of a ketone to form a gem-diol hydrate is known to be highly sensitive to substituents. Consider the two equilibria:
Tags:anomeric effects, ELF, free energy difference, interaction energy, Interesting chemistry, NBO, O Lp, Tutorial material
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Chemistry gets complex very rapidly. Consider the formula CH3NO as the topic for a tutorial in introductory chemistry. I challenge my group (of about 8 students) to draw as many different molecules as they can using exactly those atoms. I imply that perhaps each of them might find a different structure; this normally brings disbelieving expressions to their faces.
Tags:/RT, anomeric effects, arrow pushing, configurational isomer, conformational somer, double bond equivalent, electron octet, entwined systems, free energy barrier, General, Jan Jensen, optical isomerism, pericyclic reaction, resonance isomer, stereochemical, stereoelectronic, tautomers
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