Way back in 2010, I was writing about an experience I had just had during an organic chemistry tutorial, which morphed into speculation as to whether a carbon atom might sustain a quadruple bond to nitrogen. A decade on, and possibly approaching 100 articles by many authors on the topic, quadruple bonds to carbon continue to fascinate. Now an article as appeared[1] repeating this speculation for a carbon to iron quadruple bond,‡ in the very simple species C⩸Fe(CO)3 (see also a Rh-B equivalent[2]). This is particularly exciting because of the very real prospect of synthesising this species and perchance getting a crystal structure (something not possible with most of the other quadruply bonded carbon systems studied to date).
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References
- A.J. Kalita, S.S. Rohman, C. Kashyap, S.S. Ullah, and A.K. Guha, "Transition metal carbon quadruple bond: viability through single electron transmutation", Physical Chemistry Chemical Physics, vol. 22, pp. 24178-24180, 2020. https://doi.org/10.1039/d0cp03436c
- L.F. Cheung, T. Chen, G.S. Kocheril, W. Chen, J. Czekner, and L. Wang, "Observation of Four-Fold Boron–Metal Bonds in RhB(BO<sup>–</sup>) and RhB", The Journal of Physical Chemistry Letters, vol. 11, pp. 659-663, 2020. https://doi.org/10.1021/acs.jpclett.9b03484