Archive for October, 2020

Room-temperature superconductivity in a carbonaceous sulfur hydride!

Saturday, October 17th, 2020

The title of this post indicates the exciting prospect that a method of producing a room temperature superconductor has finally been achived[1]. This is only possible at enormous pressures however; >267 gigaPascals (GPa) or 2,635,023 atmospheres.

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References

  1. E. Snider, N. Dasenbrock-Gammon, R. McBride, M. Debessai, H. Vindana, K. Vencatasamy, K.V. Lawler, A. Salamat, and R.P. Dias, "Room-temperature superconductivity in a carbonaceous sulfur hydride", Nature, vol. 586, pp. 373-377, 2020. http://dx.doi.org/10.1038/s41586-020-2801-z

Trimerous pericyclic reactions.

Thursday, October 8th, 2020

I occasionally spot an old blog that emerges, if only briefly, as “trending”. In this instance, only the second blog I ever wrote here, way back in 2009 as a follow up to this article.[1] With something of that age, its always worth revisiting to see if any aspect needs updating or expanding, given the uptick in interest. It related to the observation that there can be more than one way of expressing the “curly arrows” for some pericyclic reactions. These alternatives may each represent different types of such reactions, hence leading to a conundrum for students of how to label the mechanism. I had noted in that blog that I intended to revisit the topic and so a mere eleven years later here it is!

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References

  1. H.S. Rzepa, "The Aromaticity of Pericyclic Reaction Transition States", Journal of Chemical Education, vol. 84, pp. 1535, 2007. http://dx.doi.org/10.1021/ed084p1535