I have previously looked at the topic of hydrogen bonding interactions from the hydrogen of chloroform Here I generalize C-H…O interactions by conducting searches of the CSD (Cambridge structure database) as a function of the carbon hybridisation. I am going to jump straight to a specific molecule XEVJIR (DOI: 10.5517/cc5fgpq) identified from the searches appended to this post as interesting for further inspection.[cite]10.1021/jo001484k[/cite]
Archive for July, 2019
CH…O hydrogen bonding competing with layered dispersion attractions.
Friday, July 19th, 2019Metadata. Why?
Tuesday, July 2nd, 2019I have had some interesting discussions recently regarding metadata. What emerges is that it can be quite a broadly defined concept and it is clear that a variety of answers might be obtained when asking the simple question “what is it useful for?” Here I set out some of my answers to that question.