Posts Tagged ‘zwitterion’

The dipole moments of highly polar molecules: glycine zwitterion.

Saturday, December 24th, 2016
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The previous posts produced discussion about the dipole moments of highly polar molecules. Here to produce some reference points for further discussion I look at the dipole moment of glycine, the classic zwitterion (an internal ion-pair).

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Some fun with no-go areas of chemistry: cyclobutadiene.

Sunday, September 18th, 2011
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Organic chemistry has some no-go areas, where few molecules dare venture. One of them is described by a concept known as anti-aromaticity. Whereas aromatic molecules are favoured species, their anti-equivalent is avoided. I previously illustrated this (Hückel rule) with cyclopropenium anion. Now I take a look at cyclobutadiene, for which the π-system is said to be iso-electronic (where two electrons in a double bond have replaced the carbanion lone pair).

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