Recollect, Robinson was trying
to explain why the nitroso group appears to be an o/p director of aromatic electrophilic substitution. Using σ/π orthogonality, I suggested that the (first ever) curly arrows as he drew them could not be the complete story, and that a transition state analysis would be needed. Here it is.
Posts Tagged ‘o/p director’
The first curly arrows. The dénouement.
Monday, July 23rd, 2012Tags: free energy activation barrier, σ/π orthogonality, nitrosyl, non-polar media, o/p director, o/p director of aromatic electrophilic substitution
Posted in Historical, Interesting chemistry, Reaction Mechanism, Tutorial material | 7 Comments »
