Posts Tagged ‘non-polar media’

The first curly arrows. The dénouement.

Monday, July 23rd, 2012
No Gravatar

Recollect, Robinson was trying to explain why the nitroso group appears to be an o/p director of aromatic electrophilic substitution. Using σ/π orthogonality, I suggested that the (first ever) curly arrows as he drew them could not be the complete story, and that a transition state analysis would be needed. Here it is.