Posts Tagged ‘Molecule’

George Olah and the norbornyl cation.

Friday, March 10th, 2017
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George Olah passed away on March 8th. He was part of the generation of scientists in the post-war 1950s who had access to chemical instrumentation that truly revolutionised chemistry. In particular he showed how the then newly available NMR spectroscopy illuminated structures of cations in solvents such “Magic acid“. The obituaries will probably mention his famous “feud” with H. C. Brown over the structure of the norbornyl cation (X=CH2+), implicated in the mechanism of many a solvolysis reaction that characterised the golden period of physical organic chemistry just before and after WWII. 

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The H4 (2+) dication and its bonding.

Wednesday, February 15th, 2017
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This post arose from a comment attached to the post on Na2He and relating to peculiar and rare topological features of the electron density in molecules called non-nuclear attractors. This set me thinking about other molecules that might exhibit this and one of these is shown below.

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Braiding a molecular knot with eight crossings.

Friday, January 20th, 2017
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This is one of those posts of a molecule whose very structure is interesting enough to merit a picture and a 3D model. The study[1] reports a molecular knot with the remarkable number of eight crossings.

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References

  1. J.J. Danon, A. Krüger, D.A. Leigh, J. Lemonnier, A.J. Stephens, I.J. Vitorica-Yrezabal, and S.L. Woltering, "Braiding a molecular knot with eight crossings", Science, vol. 355, pp. 159-162, 2017. http://dx.doi.org/10.1126/science.aal1619

Molecules of the year? Pnictogen chains and 16 coordinate Cs.

Monday, December 19th, 2016
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I am completing my survey of the vote for molecule of the year candidates, which this year seems focused on chemical records of one type or another.

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