Posts Tagged ‘kinetic energy density’

Are diazomethanes hypervalent molecules? Probably, but in an unexpected way!

Saturday, December 23rd, 2017
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A recently published review on hypervalency[1] introduced a very simple way of quantifying the effect. One of the molecules which was suggested to be hypervalent using this method was diazomethane. Here I take a closer look.

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References

  1. M.C. Durrant, "A quantitative definition of hypervalency", Chemical Science, vol. 6, pp. 6614-6623, 2015. http://dx.doi.org/10.1039/C5SC02076J

Ammonide: an alkalide formed from ammonia and resembling an electride.

Sunday, December 17th, 2017
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Alkalides are anionic alkali compounds containing e.g. sodide (Na), kalide (K), rubidide (Rb) or caeside (Cs). Around 90 examples can be found in the Cambridge structure database (see DOI: 10.14469/hpc/3453  for the search query and results). So what about the ammonium analogue, ammonide (NH4)? A quick search of Scifinder drew a blank! So here I take a look at this intriguingly simple little molecule.

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The weirdest bond of all? Laplacian isosurfaces for [1.1.1]Propellane.

Wednesday, July 21st, 2010
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In this post, I will take a look at what must be the most extraordinary small molecule ever made (especially given that it is merely a hydrocarbon). Its peculiarity is the region indicated by the dashed line below. Is it a bond? If so, what kind, given that it would exist sandwiched between two inverted carbon atoms?

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