Posts Tagged ‘helical metal wire’

Anapolar ring currents: a [144]-Annulene.

Friday, February 1st, 2013
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This is a recently published[1] (hypothetical) molecule which has such unusual properties that I cannot resist sharing it with you. It is an annulene with 144 all-cis CH groups, being a (very) much larger cousin of (also hypothetical) systems mooted in 2009[2],[3].



  1. R.J.F. Berger, "Prediction of a Cyclic Helical Oligoacetylene Showing Anapolar Ring Currents in the Magnetic Field", Zeitschrift für Naturforschung B, vol. 67, 2012.
  2. S.M. Rappaport, and H.S. Rzepa, "Intrinsically Chiral Aromaticity. Rules Incorporating Linking Number, Twist, and Writhe for Higher-Twist Möbius Annulenes", J. Am. Chem. Soc., vol. 130, pp. 7613-7619, 2008.
  3. C.S. Wannere, H.S. Rzepa, B.C. Rinderspacher, A. Paul, C.S.M. Allan, H.F. Schaefer, and P.V.R. Schleyer, " The Geometry and Electronic Topology of Higher-Order Charged Möbius Annulenes † ", J. Phys. Chem. A, vol. 113, pp. 11619-11629, 2009.