Comments on: Dynamic effects in nucleophilic substitution at trigonal carbon.

By: The mechanism of the Birch reduction. Part 1. « Henry Rzepa

The mechanism of the Birch reduction. Part 1. « Henry Rzepa — Sun, 02 Dec 2012 10:00:06 +0000

[...] then I argue that the model should include the positive counter-ion. This is very often simply not included, on the grounds that it “probably does not influence things”. Well, not on this blog! [...]

By: Thalidomide. The role of water in the mechanism of its aqueous racemisation. « Henry Rzepa

Sat, 10 Nov 2012 21:48:34 +0000

[...] enolisation pathway. As with the reaction of dichlorobuteneone with tolyl-thiolate about which I wrote in another post, the authors of the thalidomide study[1] modelled this route by introducing a solvated hydroxide [...]

By: Dynamic effects in nucleophilic substitution at trigonal carbon (with Na+). « Henry Rzepa

Thu, 19 Jul 2012 12:43:20 +0000

[...] Henry Rzepa Chemistry with a twist « Dynamic effects in nucleophilic substitution at trigonal carbon. [...]